Production of 5-(chloromethyl)furan-2-carbonyl chloride and furan-2,5-dicarbonyl chloride from biomass-derived 5-(chloromethyl)furfural (CMF)

被引：0
|
作者：
Dutta, Saikat [1 ]
Wu, Linglin [1 ]
Mascal, Mark [1 ]
机构：
[1] Univ Calif Davis, Dept Chem, Davis, CA 95616 USA
来源：
GREEN CHEMISTRY | 2015年 / 17卷 / 07期
关键词：
CONVERSION;
D O I：
10.1039/c5gc00936g
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Acid chloride derivatives of 5-(chloromethyl) furan-2-carboxylic acid and furan-2,5-dicarboxylic acid (FDCA) can be produced in high yield by treatment of the precursor aldehydes 5-(chloromethyl) furfural (CMF) and 2,5-diformylfuran (DFF) with tert-butyl hypochlorite, which is inexpensively prepared from commercial bleach and tert-butanol. 5-(Chloromethyl) furan-2-carbonyl chloride (CMFCC) and furan-2,5-dicarbonyl chloride (FDCC) are highly useful intermediates for the production of furoate ester biofuels and polymers of FDCA.
引用
收藏
页码：3737 / 3739
页数：3
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