Synthesis of thiocarbamates via selenium-mediated carbonylation of aniline with thiols

被引：0
|
作者：
Zhang Xiao-Peng [1 ,2 ]
Lu Shi-Wei [1 ]
机构：
[1] Chinese Acad Sci, Dalian Inst Chem Phys, Natl Engn Res Ctr Catalysis, Dalian 116011, Peoples R China
[2] Henan Normal Univ, Coll Chem & Environm Sci, Xinxiang 453007, Peoples R China
来源：
CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE | 2008年 / 29卷 / 06期
关键词：
selenium; aniline; thiol; carbonylation; thiocarbarnate;
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
In order to develop a new and facile route to the syntheses of thiocarbamates, selenium-mediated carbonylation of aniline with thiols was studied. Mediated by selenium, aniline reacted readily with carbon monooxide and thiols to afford thiocarbamates under the conditions of ambient temperature and atmospheric pressure. The results show that the reaction can proceed well to thiocarbamates in high yields with less hindered alkyl thiols. Selenium could be easily recovered and recycled.
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页码：1137 / 1140
页数：4
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