A highly dl-stereoselective pinacolization of aromatic aldehydes mediated by titanium trichloride in dichloromethane

被引：65
|
作者：
Clerici, A [1 ]
Clerici, L [1 ]
Porta, O [1 ]
机构：
[1] POLITECN MILAN,DIPARTIMENTO CHIM,I-20133 MILAN,ITALY
来源：
TETRAHEDRON LETTERS | 1996年 / 37卷 / 17期
关键词：
D O I：
10.1016/0040-4039(96)00462-5
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Aromatic aldehydes are stereoselectively coupled to dl-hydrobenzoins on treatment with anhydrous TiCl3/CH2Cl2 solution at room temperature. The observed stereochemistry is briefly discussed in term of Ti(IV)-bridging control. (C) 1986 Elsevier Science Ltd.
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收藏
页码：3035 / 3038
页数：4
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