Characterization and catalytic properties of supported nickel molybdenum nitrides for hydrodenitrogenation

被引：0
|
作者：
Wang, YH [1 ]
Li, W [1 ]
Zhang, MH [1 ]
Guan, NJ [1 ]
Tao, KY [1 ]
机构：
[1] Nankai Univ, Dept Chem, Inst New Catalyt Mat Sci, Tianjin 300071, Peoples R China
来源：
APPLIED CATALYSIS A-GENERAL | 2001年 / 215卷 / 1-2期
关键词：
XRD; TPR; XPS; NiMoNx/gamma-Al2O3; HDN; 3-methyl pyridine;
D O I：
10.1016/S0926-860X(01)00537-3
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The characterization and hydrodenitrogenation activity of 3-methyl pyridine have been obtained. The results from the characterization techniques (X-ray diffraction (XRD), temperature-programmed reaction (TPR) and XPS) were used to illustrate the structure, surface reduction properties and the role of Ni metal in the reaction. The NiMoNx/gamma -Al2O3 catalyst is more active than a Mo2N/gamma -Al2O3 catalyst with the same MoO3 loading. Mo2N, Ni3Mo3N and Ni metal are formed in the NiMoNx/gamma -Al2O3 catalyst; moreover, the synergy among them is probably responsible for the high activity of NiMoNx/gamma -Al2O3 catalyst. The addition of Ni metal enhances the reducibility of Mo2N/gamma -Al2O3 phase and also promotes the KDN activity. The reasons for reduction before reaction and the surface ion state changes during reduction are illustrated by XPS techniques. (C) 2001 Elsevier Science B.V. All rights reserved.
引用
收藏
页码：39 / 45
页数：7
相关论文
共 50 条
  • [1] TPR and TPD studies and carbazole hydrodenitrogenation activity of supported molybdenum nitrides.
    Nagai, M
    Goto, Y
    Uchino, O
    Omi, S
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1997, 213 : 69 - PETR
  • [2] Catalytic properties of nickel molybdenum sulphide supported on zirconia
    Duchet, J. C.
    Tilliette, M. J.
    Cornet, D.
    Vivier, L.
    Perot, G.
    Bekakra, L.
    Moreau, C.
    Szabo, G.
    CATALYSIS TODAY, 1991, 10 (04) : 579 - 592
  • [3] Catalytic properties of nickel molybdenum sulphides supported on nickel and magnesium aluminates
    Duchet, J. C.
    Gnofam, N.
    Lemberton, J. L.
    Perot, G.
    Bekakra, L.
    Moreau, C.
    Joffre, J.
    Kasztelan, S.
    Grimblot, J.
    CATALYSIS TODAY, 1991, 10 (04) : 593 - 612
  • [4] SURFACE AND CATALYTIC PROPERTIES OF MOLYBDENUM NITRIDES
    THOMPSON, LT
    COLLING, CW
    CHOI, D
    DEMCZYK, BG
    CHOI, JG
    LANIECKI, M
    BREYSSE, M
    DJEGAMARIADASSOU, G
    LECLERCQ, L
    SERMON, PA
    NAGAI, M
    WELLS, PB
    GRIMBLOT, J
    PRINS, R
    STUDIES IN SURFACE SCIENCE AND CATALYSIS, 1993, 75 : 941 - 954
  • [5] Surface properties and fractal approach to molybdenum nitrides and their surface activity for hydrodenitrogenation
    Nagai, A
    Yamamoto, Y
    Aono, R
    COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 2004, 241 (1-3) : 257 - 263
  • [6] CATALYTIC HYDRODENITROGENATION BY MOLYBDENUM CARBIDE AND NITRIDE
    SAJKOWSKI, DJ
    OYAMA, ST
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1990, 199 : 30 - PETR
  • [7] MORPHOLOGICAL, ELECTRONIC AND CATALYTIC PROPERTIES OF SILICA-SUPPORTED NICKEL AND NICKEL-MOLYBDENUM CATALYSTS
    KADINOV, G
    PRALIAUD, H
    PRIMET, M
    MARTIN, GA
    APPLIED CATALYSIS, 1984, 10 (01): : 63 - 76
  • [8] Catalytic activities and surface properties of zeolite-supported molybdenum nitrides for NO reduction with H2
    Shi, C
    Zhu, AM
    Yang, XF
    Au, CT
    APPLIED CATALYSIS A-GENERAL, 2005, 293 : 83 - 90
  • [9] COMPARISON OF CARBON AND ALUMINA SUPPORTED NICKEL-MOLYBDENUM SULFIDE CATALYSTS IN PARALLEL HYDRODENITROGENATION AND HYDRODESULFURIZATION
    HILLEROVA, E
    VIT, Z
    ZDRAZIL, M
    SHKUROPAT, SA
    BOGDANETS, EN
    STARTSEV, AN
    APPLIED CATALYSIS, 1991, 67 (02): : 231 - 236
  • [10] Hydrodenitrogenation of quinoline over mechanical mixtures of sulphided cobalt-molybdenum and nickel-molybdenum alumina supported catalysts
    Moreau, C.
    Bekakra, L.
    Durand, R.
    Geneste, P.
    CATALYSIS TODAY, 1991, 10 (04) : 681 - 687
12345