Silica-alumina-supported transition metal sulphide catalysts for deep hydrodesulphurization

Deep hydrodesulphurization (HDS) of dibenzothiophene (DBT) and gas-oil has been carried out on amorphous-silica-alumina (ASA)-supported transition metal sulphides (TMS) under conditions which approach industrial practice. The activity and selectivity of the binary Ni-, Ru- and Pd-promoted Mo catalysts were compared with the monometallic ones (Ru, Ir, Pd. Ni, Mo on ASA). For both HDS of DBT and gas-oil, the observed activity trends were similar; thus, all catalysts were more active with model feed than with gas-oil, and less active than commercial CoMo/Al2O3. The binary catalysts showed larger activity than monometallic ones, with Ni-Mo catalyst being more effective than Ru-Mo or Pd-Mo. For Ni-Mo sample, the X-ray photoelectron and temperature-programmed reduction techniques confirmed that incorporation of Mo minimises metal-support interaction, although the formation of nickel hydrosilicate was not prevented. The consecutive impregnation of calcined Mo/ASA catalyst with precursor solution followed by calcination enhances molybdenum surface exposure in binary samples. As a consequence, the temperature of reduction of MoO3 to molybdenum suboxides is decreased. (C) 2003 Elsevier B.V. All rights reserved.