Mechanochemical processes with the reaction-induced mechanical activation. Chemo-mechanochemical effect

被引：15
|
作者：
Boldyrev, V. V. [1 ]
机构：
[1] Russian Acad Sci, Siberian Branch, Inst Solid State Chem & Mechanochem, 18 Ul Kutateladze, Novosibirsk 630128, Russia
来源：
RUSSIAN CHEMICAL BULLETIN | 2018年 / 67卷 / 06期
关键词：
mechanochemistry; mechanical activation; chemo-mechanochemical effect; feedback in solid-state processes; mechanochemical activation as a result of the reaction itself; reactivity of solids; SOLID-STATE REACTIONS; THERMAL-DECOMPOSITION; INTERCALATION COMPOUNDS; POTASSIUM-PERMANGANATE; AMMONIUM-PERCHLORATE; STATIONARY FRONT; STRESS EVOLUTION; DRIFT KINETICS; LITHIUM-SALTS; LOCAL STRESS;
D O I：
10.1007/s11172-018-2162-z
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The review addresses the special case of mechanical activation of solid-state chemical reactions when the stress field, strain, and defects in crystals are induced by the chemical reaction itself rather than by the external mechanical impact (chemo-mechanochemical (CMC) effect). This review presents the analysis and state-of-the-art of research activities in this area. Different cases of the CMC effect in homogeneous and heterogeneous systems are considered: with or without changes in the chemical composition, with or without formation of solid products, etc.
引用
收藏
页码：933 / 948
页数：16
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