Dipolar orientation stabilities of hybrid films for second-order nonlinear optical applications

被引：6
|
作者：
Chen, Lujian [1 ]
Jin, Xuefeng [1 ]
Cui, Yuanjing [1 ]
Gao, Junkuo [1 ]
Qian, Guodong [1 ]
Wang, Minquan [1 ]
机构：
[1] Zhejiang Univ, Dept Mat Sci & Engn, State Key Lab Silicon Mat, Hangzhou 310027, Peoples R China
来源：
JOURNAL OF SOL-GEL SCIENCE AND TECHNOLOGY | 2007年 / 43卷 / 03期
基金：
中国国家自然科学基金; 中国博士后科学基金;
关键词：
second harmonic generation; poled polymer; sol-gel; thin film;
D O I：
10.1007/s10971-007-1582-2
中图分类号：
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号：
0805 ; 080502 ;
摘要：
Organic-inorganic hybrid films containing nonlinear optical (NLO) active chromophores were prepared through the polyaddition of methacrylate and hydrolytic polycondensation of sila-functional alkoxy groups of 3-(trimethoxysilyl)propyl methacrylate (TSPM) which is capable of forming carbon-carbon and siloxane chains, respectively. The NLO-active chromophores are designed and synthesized to be covalently grafted to the carbon-carbon or the siloxane chains. The comparative study of the two different incorporation methods reveals that the poled hybrid film with NLO-active chromophores bonded to siloxane chains would possess a more stable dipolar orientation.
引用
收藏
页码：329 / 335
页数：7
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