Trimethylsilyl-Induced N-O Bond Cleavage in Nitrous Oxide-Derived Aminodiazotates

被引：3

作者：

Liu, Yizhu ^{[1
]}

Eymann, Leonard Y. M. ^{[1
]}

Solari, Euro ^{[1
]}

Tirani, Farzaneh Fadaei ^{[1
]}

Scopelliti, Rosario ^{[1
]}

Severin, Kay ^{[1
]}

机构：

[1] Ecole Polytech Fed Lausanne, Inst Sci & Ingn Chim, CH-1015 Lausanne, Switzerland

来源：

INORGANIC CHEMISTRY | 2018年 / 57卷 / 19期

关键词：

HETEROCYCLIC CARBENES; ORGANIC AZIDES; COMPLEXES; CYCLOADDITION; DIAZOMETHAN; GENERATION; REDUCTION; BISAMIDES; FIXATION; IRIDIUM;

D O I：

10.1021/acs.inorgchem.8b02129

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The chemical activation of nitrous oxide (N2O) typically results in O-atom transfer and the extrusion of N-2 gas. In contrast, reactions of N-trimethylsilyl (TMS)-substituted amides with N2O give inorganic or organic azides, with concomitant formation of silanols or siloxanes. N-TMS-substituted amides are also able to induce N-O bond cleavage in N2O-derived dialkylaminodiazotates, generating tetrazene salts. These results indicate the potential of silyl groups in devising transformations, in which N2O acts as an N-atom donor.

引用

页码：11859 / 11863

页数：5

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