Rh-N-heterocyclic carbene (NHC) complex-catalyzed addition of phenylboronic acid to N-sulfonyl and N-phosphinoyl aldimines

被引：4
|
作者：
Md, Abu Bakar [1 ]
Suzuki, Yurniko [1 ]
Sato, Masayuki [1 ]
机构：
[1] Univ Shizuoka, Sch Pharmaceut Sci, Suruga Ku, Shizuoka 4228526, Japan
来源：
CHEMICAL & PHARMACEUTICAL BULLETIN | 2008年 / 56卷 / 07期
关键词：
N-heterocyclic carbene; rhodium; phenylboronic acid; addition reaction; N-sulfonylarylimine; N-phosphinoylarylimine;
D O I：
10.1248/cpb.56.973
中图分类号：
R914 [药物化学];
学科分类号：
100701 ;
摘要：
Rh-N-heterocyclic carbene (NHC) complexes were generated in situ from imidazolium salts, [RhCl(cod)](2) and t-BuOK in dioxane. In the presence of a catalytic amount of Rh-NHC complexes, the addition reaction of phenylboronic acid to N-sulfonylarylimines and N-phosphinyolarylimines gave the corresponding amines in high yields.
引用
收藏
页码：973 / 976
页数：4
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