Inorganic polymerization in a non-ionic lyotropic lamellar phase

被引:2
|
作者
Porcar, L [1 ]
Marignan, J [1 ]
Gulik-Krzywicki, T [1 ]
机构
[1] Univ Montpellier 2, UMR UM2 CNRS 5581, Dynam Phases Condensees Grp CC26, F-34095 Montpellier 5, France
关键词
inorganic gelation; lamellar phase; freeze fracture; small angle X-ray scattering (SAXS);
D O I
10.1023/A:1008611607580
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Silicon tetramethoxide was polymerized within a nonionic lyotropic lamellar phase. After gelation, the birefringence of the sample is preserved and polarized light optical microscope observations reveal no segregation. High Resolution Small Angle X-ray Scattering patterns of the gel shows Bragg peaks characteristic of a layered structure. Freeze fracture experiments on the lamellar gel show stacks of parallel bilayers. The experimental observations indicate that the silica is located in the lamellar structure.
引用
收藏
页码:99 / 102
页数:4
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