Conversion of poplar into bio-oil via subcritical hydrothermal liquefaction: Structure and antioxidant capacity

被引:30
|
作者
Wu, Xiao-Fei [1 ]
Zhou, Qian [1 ]
Li, Ming-Fei [1 ]
Li, Shu-Xian [1 ]
Bian, Jing [1 ]
Peng, Feng [1 ]
机构
[1] Beijing Forestry Univ, Beijing Key Lab Lignocellulos Chem, Beijing 100083, Peoples R China
基金
中国国家自然科学基金;
关键词
Hydrothermal liquefaction; Poplar; Bio-oil; Antioxidant capacity; SUPERCRITICAL ETHANOL; RICE STRAW; WATER; BIOMASS; PRODUCTS; SOLVENTS; L; CARBONIZATION; PRETREATMENT; METHODOLOGY;
D O I
10.1016/j.biortech.2018.09.032
中图分类号
S2 [农业工程];
学科分类号
0828 ;
摘要
Subcritical hydrothermal liquefaction of poplar was performed at 220-280 degrees C, and the liquid phase produced was extracted by ethyl acetate to obtain light oil (LO), which contained LO1 (water-soluble) and LO2 (ethyl acetate-soluble). The residue was further extracted with acetone to produce heavy oil (HO) and solid residue (SR). The highest bio-oil yield of 19.88% was obtained at 260 degrees C. The HO produced at 260 degrees C had the highest content of C (69.13%) and the higher heating value was 27.97 MJ/kg. The O/C and H/C ratios of LO were higher than those of HO due to less aromatics in LO. Oxidative inhibition rates of bio-oils, measured in DPPH-ethanol solution at a concentration of 0.1 mg/mL, reached 60.76% for LO1 while 90.29% and 90.85% for LO2 and HO, respectively. The bio-oil with good antioxidant activity can be utilized as an additive in bio-diesel to improve oxidation stability.
引用
收藏
页码:216 / 222
页数:7
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