Homoleptic lanthanide complexes of chelating phosphanamides - An experimental and theoretical study

被引：1

作者：

Wetzel, TG ^{[1
]}

Dehnen, S ^{[1
]}

Roesky, PW ^{[1
]}

机构：

[1] Univ Karlsruhe, Inst Anorgan Chem, D-76128 Karlsruhe, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 1999年 / 38卷 / 08期

关键词：

ab initio calculations; chelates; density functional calculations; lanthanides; phosphanamides;

D O I：

10.1002/(SICI)1521-3773(19990419)38:8<1086::AID-ANIE1086>3.0.CO;2-E

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Four chelating ligands are present in the first phosphanamide complexes of Group 3 metals and the lanthanides (see structure shown). However, these ligands coordinate to form a distorted molecular structure. The compounds were characterized by single-crystal X-ray structure analysis and quantum- mechanical investigations with density functional theory and MP2 methods.

引用

页码：1086 / 1088

页数：3

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