Hysteresis phenomena in heterogeneous exothermal catalytic reactions and methods for decreasing the overheating of catalyst nanoclusters

被引：7

作者：

Subbotin, Alexander N. ^{[1
]}

Subbotina, Irina R. ^{[1
]}

Golosman, Evgeny Z. ^{[2
]}

机构：

[1] Russian Acad Sci, ND Zelinskii Organ Chem Inst, Moscow 119991, Russia

[2] Novomoskovsk Inst Nitrogen Ind, Novomoskovsk 301650, Tula Region, Russia

来源：

MENDELEEV COMMUNICATIONS | 2015年 / 25卷 / 03期

关键词：

CO OXIDATION;

D O I：

10.1016/j.mencom.2015.05.020

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Hysteresis in hydrogenation reactions has been found for the first time. A concept of the local overheating of active nanoparticles in a catalyst due to hindered reaction heat removal has been suggested to explain the origins of the appearance of a hysteresis loop.

引用

页码：216 / 218

页数：3

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