Preparation and structures of the mixed-metal clusters Pt2M2Se2Cl2(PPh3)4 (M = Cu, Ag) and Pd2Au2Se2(SeH)2(PPh3)4.: An entry to ternary clusters

被引：16

作者：

Harvey, PD ^{[1
]}

Eichhöfer, A ^{[1
]}

Fenske, D ^{[1
]}

机构：

[1] Univ Karlsruhe, Inst Inorgan Chem, D-76128 Karlsruhe, Germany

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1998年 / 23期

关键词：

D O I：

10.1039/a807414c

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Both cis- and trans-Pt(PPh3)(2)Cl-2 react with Se(SiMe3)(2) and CuCl or AgO2CR (R = Me, Ph) in THF to form the mixed-metal clusters Pt2M2Se2Cl2(PPh3)(4) (M = Cu or Ag, respectively), and likewise Au(PPh3)Cl reacts with Pd(acac)(2), to form Pd2Au2Se2(SeH)(2)(PPh3)(4).

引用

页码：3901 / 3903

页数：3

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