(Terpyridine)(acetylacetonate)ruthenium(II) complex with a zwitterionic form of phosphoniophenylcyanamide ligand

被引:4
|
作者
Dudd, L
Hart, M
Ring, D
Sondaz, E
Bonvoisin, J
Coppel, Y
机构
[1] CNRS, CEMES, Mol Elect Grp, F-31055 Toulouse 4, France
[2] CNRS, LCC, UPR 8241, F-31077 Toulouse 4, France
关键词
ruthenium(II) complex; cyanamide; NMR; zwitterion; phosphonium;
D O I
10.1016/j.inoche.2003.08.016
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The complex [Ru(tpy)(acac)(PPh(4)cyd)][PF6] (where tpy: 2,2':6',2"-terpyridine, acac: acetylacetone and PPh4cyd: 4-triphenylphosphoniophenylcyanamide) has been synthesized. It contains the zwitterionic form of the phosphoniophenylcyanamide ligand. Characterizations were carried out using IR, ES-MS, UV-Vis, electrochemistry and H-1, C-13 and P-31 NMR spectroscopy. (C) 2003 Elsevier B.V. All rights reserved.
引用
收藏
页码:1400 / 1405
页数:6
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