Kinetics of polyol oxidation by ozone in aqueous solutions

被引：3
|
作者：
Zimin, YS [1 ]
Trukhanova, NV [1 ]
Strel'tsova, IV [1 ]
Komissarov, VD [1 ]
机构：
[1] Bashkortostan State Univ, Ufa 450007, Bashkortostan, Russia
来源：
KINETICS AND CATALYSIS | 2000年 / 41卷 / 06期
关键词：
Oxidation; Alcohol; Ethylene; Physical Chemistry; Aqueous Solution;
D O I：
10.1023/A:1026608700202
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Spectrophotometry is applied to study the oxidation of ethylene glycol, triethylene glycol, glycerol, etriol, pentaerithritol and mannitol by ozone in aqueous solutions at 277-304 K. Rate constants and activation parameters of the reaction are measured. It is proposed that the oxidation of these alcohols by ozone occurs via the same mechanism. The formation of an intermediate complex is a rate-limiting step in the case of diols; the decomposition of the complex is a rate-limiting step for tri- to hexatomic alcohols.
引用
收藏
页码：749 / 752
页数：4
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