Synthesis and characterisation of [AlMen{Si(SiMe3)3}3-n(thf)] (n=1 or 2)

被引：4

作者：

Farwell, James D. ^{[1
]}

Hitchcock, Peter B. ^{[1
]}

Lappert, Michael F. ^{[1
]}

机构：

[1] Univ Sussex, Dept Chem, Brighton BN1 9QJ, E Sussex, England

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2007年 / 692卷 / 24期

关键词：

aluminium; silyl complexes; structure; nitrile insertion;

D O I：

10.1016/j.jorganchem.2007.08.018

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The crystalline compounds [AlMen{Si(SiMe3)(3)}(3-n)(thf)] [n = 2(1) or 1 (2)] were prepared from the lithium sisyl [Li{Si(SiMe3)(3)}(thf)(3)] (A) and the appropriate methylaluminium chloride [AlCl3-nMen] in thf. The X- ray structure of 1 is reported. Unlike A or a magnesium sisyl [Mg{Si(SiMe3)(3)}(2)(thf)(2)] (B), neither 1 nor 2 underwent an insertion reaction with an alpha-H-free nitrile. (C) 2007 Elsevier B.V. All rights reserved.

引用

页码：5492 / 5494

页数：3

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