Syntheses and structures of [Ag(etu)3]2SO4 and [{Cu(etu)I}3]n (etu = ethylenethiourea):: a new μ3-S coordination mode for etu

被引：7

作者：

Jia, Dingxian ^{[1
]}

Zhang, Yong ^{[1
]}

Deng, He ^{[1
]}

Ji, Mingxia ^{[1
]}

机构：

[1] Suzhou Univ, Coll Chem & Chem Engn, Suzhou 215123, Peoples R China

来源：

JOURNAL OF COORDINATION CHEMISTRY | 2007年 / 60卷 / 7-9期

关键词：

silver(I); copper(I); ethylenethiourea; crystal structure; coordination mode;

D O I：

10.1080/00958970600927244

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

[Ag(etu)(3)](2)SO4 (1) and [{Cu(etu)I}(3)](n) (2) (etu=ethylenethiourea) have been synthesized by reaction of etu with Ag2SO4 or CuI and their crystal structures determined. In I both crystallographically independent Ag+ ions are trigonally coordinated by three monodenate etu ligands. Complex 2 is composed of a one-dimensional polymer assembled by cyclic [Cu(etu)I](3) trimers. In the [{Cu(etu)I}(3)](n), polymer, the chair-type Cu4S2I2 core is formed by mu(3)-S bridging etu ligands and this represents a new coordination mode for etu. The Cu+ ions have a distorted tetrahedral coordination geometry.

引用

页码：833 / 841

页数：9

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