A stable and high-capacity anode for lithium-ion battery: Fe2O3 wrapped by few layered graphene

被引:68
|
作者
Wang, Yukun [1 ,2 ,3 ]
Yang, Lichun [1 ,2 ,3 ]
Hu, Renzong [1 ,2 ,3 ]
Sun, Wei [1 ,2 ,3 ]
Liu, Jiangwen [1 ,2 ,3 ]
Ouyang, Liuzhang [1 ,2 ,3 ]
Yuan, Bin [1 ,2 ,3 ]
Wang, Haihui [4 ]
Zhu, Min [1 ,2 ,3 ]
机构
[1] S China Univ Technol, Sch Mat Sci & Engn, Guangzhou 510641, Guangdong, Peoples R China
[2] S China Univ Technol, Key Lab Adv Energy Storage Mat Guangdong Prov, Guangzhou 510641, Guangdong, Peoples R China
[3] S China Univ Technol, China Australia Joint Lab Energy & Environm Mat, Guangzhou 510641, Guangdong, Peoples R China
[4] S China Univ Technol, Sch Chem & Chem Engn, Guangzhou 510641, Guangdong, Peoples R China
基金
中国国家自然科学基金;
关键词
Few layered graphene; Dielectric barrier discharge plasma; Ball milling; Anode; Lithium-ion battery; ELECTROCHEMICAL PERFORMANCE; DISCHARGE PLASMA; NANOCOMPOSITE; COMPOSITE; INTERCALATION; NANOFIBERS; NANOSHEETS;
D O I
10.1016/j.jpowsour.2015.04.076
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Fe2O3 wrapped by few layered graphene nanosheets composites (Fe2O3-FLG) have been synthesized via a facile and massive one-step P-milling method, which is effective in reducing the particle size of Fe2O3 and exfoliating the graphite into FLG. The composite shows good electrochemical performance due to the tight wrapping of FLG nanosheets, which is beneficial to electric conductivity and integrity of the electrode. The sample treated under 20 h retains a reversible capacity of 758 mAh g(-1) at 200 mA g(-1) after 300 cycles, which equals to 88% of its theoretic capacity. With the superior electrochemical performance, Fe2O3-FLG composites prepared via the P-milling method could be promising as anode materials for high performance lithium-ion batteries. (c) 2015 Elsevier B.V. All rights reserved.
引用
收藏
页码:314 / 319
页数:6
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