Diphosphaborane and Metalladiphosphaborane: Ligands for Transition-Metal Chemistry

被引：7

作者：

McLellan, Ross ^{[1
]}

Ellis, David ^{[1
]}

Rosair, Georgina M. ^{[1
]}

Welch, Alan J. ^{[1
]}

机构：

[1] Heriot Watt Univ, Dept Chem, Edinburgh EH14 4AS, Midlothian, Scotland

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2011年 / 50卷 / 51期

基金：

英国工程与自然科学研究理事会;

关键词：

boron; diphosphaboranes; metalladiphosphaboranes; transition-metal complexes; MOLECULAR-STRUCTURE; CRYSTAL-STRUCTURE; COMPLEXES; PHOSPHABORANES;

D O I：

10.1002/anie.201105820

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

New ligands: The first examples of a neutral heteroborane and a neutral metallaheteroborane acting as simple Ï-bound ligands to transition metals are described. In [HCo(1,2-closo-P 2B 10H 10) 2(PEt 3) 2] (see structure, left) the P 2B 10H 10 ligand coordinates to Co through one P atom, and in I-[1,2-{HRu(p-cymene)} 2-7′,8′-nido-P 2B 9H 9]-3-(p-cymene)-3,1,2-closo-RuP 2B 9H 9 (right) both closo-RuP 2B 9 and nido-P 2B 9 cages act as bridging P:P ligands. © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：12339 / 12341

页数：3

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