Chemistry of Several Sterically Bulky Molecules with P=P, P=C, and C≡P Bond

被引：11

作者：

Yoshifuji, Masaaki ^{[1
,2
]}

机构：

[1] Tohoku Univ, Grad Sch Sci, Dept Chem, Sendai, Miyagi 9808578, Japan

[2] Univ Alabama, Coll Arts & Sci, Dept Chem & Biochem Sci, Tuscaloosa, AL 35401 USA

来源：

MOLECULES | 2022年 / 27卷 / 05期

基金：

日本学术振兴会; 美国国家科学基金会;

关键词：

steric protection; low-coordinate phosphorus compound; diphosphene; phosphaalkene; phosphaalkyne; phosphaallene; diphosphinidenecyclobutene; catalytic reaction; BEARING DIPHOSPHINIDENECYCLOBUTENE LIGANDS; X-RAY-STRUCTURE; AIR-STABLE 1,3-DIPHOSPHACYCLOBUTANE-2,4-DIYLS; COORDINATED PHOSPHORUS-COMPOUNDS; HIGHLY-ACTIVE CATALYSTS; AMINATION REACTIONS; COMPLEX BEARING; AB-INITIO; DIPHOSPHENE; CRYSTAL;

D O I：

10.3390/molecules27051557

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

Several sterically protected, low-coordinate organophosphorus compounds with P=P, P=C, and C equivalent to P bond are described in this study. Molecules such as diphosphenes, phosphaalkenes, 1-phosphaallenes, 1,3-diphosphaallenes, 3,4-diphosphinidenecyclobutenes, and phosphaalkynes are stabilized with an extremely bulky 2,4,6-tri-t-butylphenyl (Mes*) group. The synthesis, structures, physical, and chemical properties of these molecules are discussed, together with some successful applications in catalytic organic reactions.

引用

页数：21

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