Wolframite-type ZnWO4 Nanorods as New Anodes for Li-Ion Batteries

被引：75
|
作者：
Shim, Hyun-Woo [1 ]
Cho, In-Sun [2 ]
Hong, Kug Sun [2 ]
Lim, Ah-Hyeon [1 ]
Kim, Dong-Wan [1 ]
机构：
[1] Ajou Univ, Dept Mat Sci & Engn, Suwon 443749, South Korea
[2] Seoul Natl Univ, Dept Mat Sci & Engn, Seoul 151744, South Korea
来源：
JOURNAL OF PHYSICAL CHEMISTRY C | 2011年 / 115卷 / 32期
关键词：
TEMPLATE-FREE SYNTHESIS; NANOCOMPOSITE ELECTRODES; CUPROUS-OXIDE; HIGH-CAPACITY; LITHIUM; NANOWIRES; STORAGE; NANOTUBES; ZNCO2O4; FACILE;
D O I：
10.1021/jp204656v
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
A divalent wolframite-structure zinc tungstate (ZnWO4) was synthesized using a facile hydrothermal process at 180 degrees C, with pH adjustment to drive the preferential growth along the [100] direction, resulting in the formation of one-dimensional nanorods. The resulting nanorods were characterized in detail using X-ray diffraction, Raman spectroscopy, field-emission scanning electron microscopy, high-resolution transmission electron microscopy, energy-dispersive X-ray analysis, and Brunauer-Emmett-Teller measurements. In addition, the Li electroactivities of the ZnWO4 nanorods were investigated using cyclic voltammetry and galvanostatic cycling. The ZnWO4 nanorods could deliver reversibly sustained high capacities of over 420 mAh g(-1) after 150 cycles, which are much higher than those of graphite-based anodes.
引用
收藏
页码：16228 / 16233
页数：6
相关论文
共 50 条
  • [1] Ab initio study of the electronic and atomic structure of the wolframite-type ZnWO4
    Kalinko, A.
    Kuzmin, A.
    Evarestov, R. A.
    [J]. SOLID STATE COMMUNICATIONS, 2009, 149 (11-12) : 425 - 428
  • [2] Wet chemical synthesis and characterization of nanocrystalline ZnWO4 for application in Li-ion batteries
    Ilango, P. Robert
    Prasanna, K.
    Jo, Yong Nam
    Santhoshkumar, P.
    Lee, Chang Woo
    [J]. MATERIALS CHEMISTRY AND PHYSICS, 2018, 207 : 367 - 372
  • [3] Hydrothermal synthesis, characterization, and optical properties of wolframite ZnWO4 nanorods
    Siriwong, Parada
    Thongtem, Titipun
    Phuruangrat, Anukorn
    Thongtem, Somchai
    [J]. CRYSTENGCOMM, 2011, 13 (05): : 1564 - 1569
  • [4] Tuning Silicon Nanorods for Anodes of Li-Ion Rechargeable Batteries
    Au, Ming
    Garcia-Diaz, Brenda
    Adams, Thad
    He, Yuping
    Zhao, Yiping
    Yassar, Reza Shahbazian
    Ghassemi, Hessam
    [J]. ELECTROCHEMISTRY OF NOVEL MATERIALS FOR ENERGY STORAGE AND CONVERSION, 2011, 33 (27): : 35 - 43
  • [5] Fabrication of core/shell ZnWO4/carbon nanorods and their Li electroactivity
    Hyun-Woo Shim
    Ah-Hyeon Lim
    Gwang-Hee Lee
    Hang-Chul Jung
    Dong-Wan Kim
    [J]. Nanoscale Research Letters, 7
  • [6] Fabrication of core/shell ZnWO4/carbon nanorods and their Li electroactivity
    Shim, Hyun-Woo
    Lim, Ah-Hyeon
    Lee, Gwang-Hee
    Jung, Hang-Chul
    Kim, Dong-Wan
    [J]. NANOSCALE RESEARCH LETTERS, 2012, 7 : 1 - 7
  • [7] ZnWO4 nanocrystals/reduced graphene oxide hybrids:Synthesis and their application for Li ion batteries
    WANG Xiao
    LI BoLong
    LIU DaPeng
    XIONG HuanMing
    [J]. Science China Chemistry, 2014, (01) : 122 - 126
  • [8] Silicon and silicon-copper composite nanorods for anodes of Li-ion rechargeable batteries
    Au, Ming
    He, Yuping
    Zhao, Yiping
    Ghassemi, Hessam
    Yassar, Reza Shahbazian
    Garcia-Diaz, Brenda
    Adams, Thad
    [J]. JOURNAL OF POWER SOURCES, 2011, 196 (22) : 9640 - 9647
  • [9] ZnWO4 nanocrystals/reduced graphene oxide hybrids: Synthesis and their application for Li ion batteries
    Wang Xiao
    Li BoLong
    Liu DaPeng
    Xiong HuanMing
    [J]. SCIENCE CHINA-CHEMISTRY, 2014, 57 (01) : 122 - 126
  • [10] ZnWO4 nanocrystals/reduced graphene oxide hybrids: Synthesis and their application for Li ion batteries
    Xiao Wang
    BoLong Li
    DaPeng Liu
    HuanMing Xiong
    [J]. Science China Chemistry, 2014, 57 : 122 - 126
12345