Synthesis and crystal structure of the copper complex {[Cu(CH3COO)2(bbtz)](H2O)2}n

被引：0

作者：

Zhang, Y ^{[1
]}

Zhang, YM ^{[1
]}

Liu, XG ^{[1
]}

Li, BL ^{[1
]}

机构：

[1] Suzhou Univ, Coll Chem & Chem Engn, Key Lab Organ Synth, Suzhou 215123, Jiangsu Prov, Peoples R China

来源：

CHINESE JOURNAL OF STRUCTURAL CHEMISTRY | 2005年 / 24卷 / 10期

关键词：

crystal structure; copper complex; triazole ligand; synthesis;

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The new copper complex {[Cu(CH3COO)(2)(bbtz)](H2O)(2)}(n) 1 (bbtz = 1,4-bis(1,2,4-triazol-i-ylmethyl)benzene) was synthesized and the structure was determined by single-crystal X-ray diffraction. Crystal data: C16H22CuN6O6, monoclinic, space group P2(1)/n, a = 12.589(5), b = 6.455(2), c = 12.677(5) angstrom, beta = 98.748(9)degrees, V = 1018.2(7) angstrom(3), M-r = 457.95, Z = 2, D-c = 1.494 g/cm(3), F(000) = 474, mu = 1.118 mm(-1), R = 0.0463 and wR = 0.0939 for 1971 observed reflections with I > 2 sigma(I). The crystal structure of 1 is a one-dimensional chain via the bridging flexible ligand bbtz.

引用

页码：1129 / 1132

页数：4

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