Energy Transfer Between Ce3+and Eu2+in Doped Sr5(PO4)3F Phosphor

被引：14
|
作者：
Shinde, K. N. [1 ]
Nagpure, I. M. [2 ]
Dhoble, S. J. [3 ]
机构：
[1] NS Sci & Arts Coll, Dept Phys, Bhadrawati 442902, India
[2] Univ Free State, Dept Phys, Bloemfontein, Free State, South Africa
[3] RTM Nagpur Univ, Dept Phys, Nagpur, Maharashtra, India
来源：
SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY | 2011年 / 41卷 / 01期
关键词：
energy transfer; photoluminescence; rare earth ion; UV excitation; XRD; LUMINESCENCE; PHOTOLUMINESCENCE; TRANSITIONS; GLASSES; IONS; EU3+; LAMP;
D O I：
10.1080/15533174.2010.538021
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Sr5(PO4)3F phosphor doped with Eu[image omitted] and Ce[image omitted] ion were prepared by combustion synthesis. Under UV excitation (254 nm) Sr5(PO4)3F:Ce exhibits Ce[image omitted] UV emission (355 nm) and under 354 nm, Sr5(PO4)3F:Eu exhibits Eu[image omitted] emission (440 nm). The aim of this article is to report energy transfer mechanism between Ce[image omitted]Eu[image omitted] ion in Sr5(PO4)3F:Ce,Eu phosphors, where Ce ion act as sensitizer and Eu act as activator. Ce emission energy band is in resonance with Eu excitation energy band. Their structures properties and photoluminescence spectra were systemically studied. This article includes synthesis of phosphor, XRD, EDS, SEM pattern of host lattice, photoluminescence behavior, and energy transfer mechanism between the two rare earth ions.
引用
收藏
页码：107 / 113
页数：7
相关论文
共 50 条
  • [1] Luminescence properties and energy transfer from Eu2+ to Tb3+ in Sr5(PO4)3F phosphor
    Sun, Jiayue
    Cui, Dianpeng
    Xue, Bing
    Sun, Guangchao
    Du, Haiyan
    ADVANCED MATERIALS AND ENGINEERING MATERIALS II, 2013, 683 : 199 - +
  • [2] Luminescence and crystallographic sites for Eu3+ ions in Sr5(PO4)3F phosphor
    Qiao, Xuebin
    Seo, Hyo Jin
    JOURNAL OF ALLOYS AND COMPOUNDS, 2014, 615 : 270 - 275
  • [3] Identification of Eu oxidation states in a doped Sr5(PO4)3F phosphor by TOF-SIMS imaging
    Swart, H. C.
    Nagpure, I. M.
    Ntwaeaborwa, O. M.
    Fisher, G. L.
    Terblans, J. J.
    OPTICS EXPRESS, 2012, 20 (15): : 17119 - 17125
  • [4] Gain saturation measurements of ytterbium-doped Sr5(PO4)3F
    Bayramian, Andy J.
    Bibeau, Camille
    Schaffers, Kathleen I.
    Marshall, Christopher D.
    Payne, Steve A.
    Applied Optics, 2000, 39 (06):
  • [5] Development of ytterbium doped Sr5(PO4)3F for the Mercury Laser project
    Bayramian, A
    Bibeau, C
    Schaffers, K
    Lawson, J
    Marshall, C
    Payne, S
    Morris, R
    ADVANCED SOLID-STATE LASERS, 1999, 26 : 635 - 641
  • [6] Gain saturation measurements of ytterbium-doped Sr5(PO4)3F
    Bayramian, AJ
    Bibeau, C
    Schaffers, KI
    Marshall, CD
    Payne, SA
    APPLIED OPTICS, 2000, 39 (06) : 982 - 985
  • [7] Preparation of Eu ions doped Sr5(PO4)3F transparent glass ceramics and their luminescence properties
    Zhang, Chenyang
    Wu, Jinhai
    Song, Jie
    Li, Xianxue
    CERAMICS INTERNATIONAL, 2024, 50 (19) : 34609 - 34615
  • [8] EU3(PO4)2 AND EU5(PO4)3F AND EU5-XCAX(PO4)3F SYSTEM
    MAYER, I
    FISCHBEI.E
    COHEN, S
    ACTA CRYSTALLOGRAPHICA SECTION A, 1972, 28 : S59 - S59
  • [9] Investigation on Nd:Sr5(PO4)3F single crystal
    Meng, XL
    Zhu, L
    Zhang, HJ
    Zhang, HZ
    Yang, ZH
    Wang, P
    Dawes, J
    Wang, CQ
    Chow, YT
    JOURNAL OF INORGANIC MATERIALS, 1998, 13 (06) : 787 - 792
  • [10] Luminescence, cathodoluminescence and Ce3+ → Eu2+ energy transfer and emission enhancement in the Sr5(PO4)3Cl:Ce3+,Eu2+ phosphor
    Zhou, Lei
    Liang, Hongbin
    Tanner, Peter A.
    Zhang, Su
    Hou, Dejian
    Liu, Chunmeng
    Tao, Ye
    Huang, Yan
    Li, Lina
    JOURNAL OF MATERIALS CHEMISTRY C, 2013, 1 (43) : 7155 - 7165
12345