Synthesis, characterization and molecular structure of Ru(II) complex with 8-hydroxyquinoline derivative

被引：6
|
作者：
Malecki, J. G. [1 ]
Serda, M. [2 ]
Musiol, R. [2 ]
Polanski, J. [2 ]
机构：
[1] Silesian Univ, Inst Chem, Dept Crystallog, PL-40006 Katowice, Poland
[2] Silesian Univ, Inst Chem, Dept Organ Chem, PL-40006 Katowice, Poland
来源：
POLYHEDRON | 2012年 / 31卷 / 01期
关键词：
(E)-8-hydroxyquinoline-2-carbaldehyde; O-benzyl oxime; Ruthenium(II) hydride carbonyl complexes; X-ray structure; UV-Vis; Luminescence; DFT; TD-DFT; CARBONYL RUTHENIUM(II) COMPLEXES; ELECTRONIC-STRUCTURES; HYDRIDE-COMPLEXES; CHEMISTRY; CRYSTAL; RUHCL(CO)(PPH3)(3); HYDROGENATION;
D O I：
10.1016/j.poly.2011.09.041
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The new (E)-8-hydroxyquinoline-2-carbaldehyde O-benzyl oxime ligand and its hydride-carbonyl complex of ruthenium was synthesized and characterized by infrared, proton and phosphorus nuclear magnetic resonance, electronic absorption and emission spectroscopy and X-ray crystallography. The experimental studies were complemented by theoretical calculations. From the electronic spectrum of the complex the Racah's and nepheloauxetic parameters are calculated. The electronic structure of the complexes, presented in particular by the density of states diagram, have been correlated with its ability to fluoresce and used to analyze the UV-Vis spectra. (C) 2011 Elsevier Ltd. All rights reserved.
引用
收藏
页码：451 / 456
页数：6
相关论文
共 50 条
  • [1] Synthesis and structural characterization of a 8-hydroxyquinoline derivative coordinated to Zn(II)
    De Freitas, Leonardo V.
    Dos Santos, Abid Lohan da S. F.
    Da Costa, Felipe C.
    Calixto, Jader B.
    Miranda, Paulo Vinicius P.
    Silva, Thamires J. J.
    Pereira, Eufrasia S.
    Rocha, Willian R.
    De Almeida, Wagner B.
    De Souza, Leonardo A.
    Freitas, Maria C. R.
    JOURNAL OF MOLECULAR STRUCTURE, 2018, 1169 : 119 - 129
  • [2] Synthesis of 8-Hydroxyquinoline Derivative and Its Zinc Complex
    Zhang, Xuejun
    Li, Shengling
    Zou, Li
    Zhang, Zhuoqiang
    Liao, Chaoqiang
    Li, Qiaoling
    JOURNAL OF COMPUTATIONAL AND THEORETICAL NANOSCIENCE, 2015, 12 (09) : 2786 - 2790
  • [3] Synthesis, characterization, and anti-corrosion properties of an 8-hydroxyquinoline derivative
    Alamshany, Zahra M.
    Ganash, Aisha A.
    HELIYON, 2019, 5 (11)
  • [4] Synthesis and performances of a tridentate 8-hydroxyquinoline derivative ligand and its zinc complex
    Li, Shan-ji
    Li, Yu
    Zhang, Jing-An
    INORGANIC CHEMISTRY COMMUNICATIONS, 2012, 20 : 334 - 339
  • [5] Synthesis and Characterization of Lathanum Complex with 8-Hydroxyquinoline by Solid State Reaction
    Kao Teng Hsueh Hsiao Hua Heush Hsueh Pao, 8 (1262):
  • [6] Synthesis and characterization of lathanum complex with 8-hydroxyquinoline by solid state reaction
    Lu, JC
    Chen, JS
    Su, QD
    Yong, KL
    CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE, 1997, 18 (08): : 1262 - 1264
  • [7] CRYSTAL AND MOLECULAR-STRUCTURE OF 8-HYDROXYQUINOLINE
    ROYCHOWDHURY, P
    DAS, BN
    BASAK, BS
    ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1978, 34 (MAR): : 1047 - 1048
  • [8] Green synthesis and characterization for 8-hydroxyquinoline magnesium
    Liu, Junchen
    Zhong, Xueming
    Wu, Shiting
    Li, Yanrong
    Xu, Yuna
    Zeng, Hongze
    MATERIALS RESEARCH EXPRESS, 2019, 6 (05):
  • [9] MOLECULAR COMPLEXES .7. CRYSTAL AND MOLECULAR STRUCTURE OF 8-HYDROXYQUINOLINE CHLORANIL COMPLEX
    PROUT, CK
    WHEELER, AG
    JOURNAL OF THE CHEMICAL SOCIETY A -INORGANIC PHYSICAL THEORETICAL, 1967, (03): : 469 - &
  • [10] Synthesis, characterization, and determination of genotoxic effect of a novel dimeric 8-hydroxyquinoline Cd(II) SCN complex
    Tunca, Hatice
    Berber, Ahmet Ali
    Canakci, Kubra
    Tuna, Murat
    Yildiz, Salih Zeki
    Aksoy, Huseyin
    DRUG AND CHEMICAL TOXICOLOGY, 2017, 40 (03) : 300 - 308
12345