Phosphonate-functionalized large pore 3-D cubic mesoporous (KIT-6) hybrid as highly efficient actinide extracting agent

被引：90

作者：

Lebed, Pablo J. ^{[1
,2
]}

de Souza, Kellen ^{[1
,2
]}

Bilodeau, Francois ^{[3
]}

Lariviere, Dominic ^{[1
,2
]}

Kleitz, Freddy ^{[1
,2
]}

机构：

[1] Univ Laval, Dept Chem, Ctr Rech Mat Avances CERMA, Quebec City, PQ G1K 7P4, Canada

[2] Ctr Rech Proprietes Interfaces & Catalyse CERPIC, Quebec City, PQ, Canada

[3] Gentilly 2 Nucl Power Plant, Hydro Quebec Prod, Gentilly, PQ G9H 3X3, Canada

来源：

CHEMICAL COMMUNICATIONS | 2011年 / 47卷 / 41期

关键词：

CHROMATOGRAPHY; SILICA; PRECONCENTRATION; ORGANOSILICAS; SEPARATION; PLUTONIUM; URINE;

D O I：

10.1039/c1cc14053a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A new type of radionuclide extraction material is reported based on phosphonate functionalities covalently anchored on the mesopore surface of 3-D cubic mesoporous silica (KIT-6). The easily prepared nanoporous hybrid shows largely superior performance in selective sorption of uranium and thorium as compared to the U/TEVA commercial resin and 2-D hexagonal SBA-15 equivalent.

引用

页码：11525 / 11527

页数：3

共 18 条

[1] 3-D ordered mesoporous KIT-6 support for effective hydrodesulfurization catalysts
Soni, K.
Rana, B. S.
Sinha, A. K.
Bhaumik, A.
Nandi, M.
Kumar, M.
Dhar, G. M.
APPLIED CATALYSIS B-ENVIRONMENTAL, 2009, 90 (1-2) : 55 - 63
[2] Dehydrogenation of homocyclic liquid organic hydrogen carriers (LOHCs) over Pt supported on an ordered pore structure of 3-D cubic mesoporous KIT-6 silica
Ahn, Chang-Il
Kwak, Yeonsu
Kim, Ah-Reum
Jang, Munjeong
Badakhsh, Arash
Cha, Junyoung
Kim, Yongmin
Jo, Young Suk
Jeong, Hyangsoo
Choi, Sun Hee
Nam, Suk Woo
Yoon, Chang Won
Sohn, Hyuntae
APPLIED CATALYSIS B-ENVIRONMENT AND ENERGY, 2022, 307
[3] Large pore phenylene-bridged mesoporous organosilica with bicontinuous cubic Ia(3)over-bard (KIT-6) mesostructure
Guo, Wanping
Kleitz, Freddy
Cho, Kanghee
Ryoo, Ryong
JOURNAL OF MATERIALS CHEMISTRY, 2010, 20 (38) : 8257 - 8265
[4] Novel one step hydrothermal synthesis of cubic Ia3d large pore 3D mesoporous In2O3/KIT-6 hybrid nanocomposite with humidity sensing applications
Jakhar, Shivani
Duhan, Surender
Nain, Sonia
JOURNAL OF POROUS MATERIALS, 2020, 27 (05) : 1253 - 1263
[5] Novel one step hydrothermal synthesis of cubic Ia3d large pore 3D mesoporous In2O3/KIT-6 hybrid nanocomposite with humidity sensing applications
Shivani Jakhar
Surender Duhan
Sonia Nain
Journal of Porous Materials, 2020, 27 : 1253 - 1263
[6] Large-Pore 3D Cubic Mesoporous (KIT-6) Hybrid Bearing a Hard-Soft Donor Combined Ligand for Enhancing U(VI) Capture: An Experimental and Theoretical Investigation
Yuan, Li-Yong
Zhu, Lin
Xiao, Cheng-Liang
Wu, Qun-Yan
Zhang, Nan
Yu, Ji-Pan
Chai, Zhi-Fang
Shi, Wei-Qun
ACS APPLIED MATERIALS & INTERFACES, 2017, 9 (04) : 3774 - 3784
[7] 3D cubic mesoporous C3N4 with tunable pore diameters derived from KIT-6 and their application in base catalyzed Knoevenagel reaction
Talapaneni, Siddulu Naidu
Ramadass, Kavitha
Ruban, Sujanya J.
Benzigar, Mercy
Lakhi, Kripal S.
Yang, Jae-Hun
Rayon, Ugo
Albahily, Khalid
Vinu, Ajayan
CATALYSIS TODAY, 2019, 324 (33-38) : 33 - 38
[8] Humidity-sensing properties of LiCl-loaded 3D cubic mesoporous silica KIT-6 composites
Zhao, Hongran
Liu, Sen
Wang, Rui
Zhang, Tong
MATERIALS LETTERS, 2015, 147 : 54 - 57
[9] Large-Pore Functionalized Mesoporous Silica Nanoparticles as Drug Delivery Vector for a Highly Cytotoxic Hybrid PlatinumAcridine Anticancer Agent
Zheng, Ye
Fahrenholtz, Cale D.
Hackett, Christopher L.
Ding, Song
Day, Cynthia S.
Dhall, Rohan
Marrs, Glen S.
Gross, Michael D.
Singh, Ravi
Bierbach, Ulrich
CHEMISTRY-A EUROPEAN JOURNAL, 2017, 23 (14) : 3386 - 3397
[10] 3D-mesoporous KIT-6 supported highly dispersed Pd nanocatalyst for dodecahydro-N-ethylcarbazole dehydrogenation
Feng, Zhaolu
Bai, Xuefeng
MICROPOROUS AND MESOPOROUS MATERIALS, 2022, 335

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