Reaction of 1,2-dialkyldiaziridines with ketenes as a new approach to cyclic and linear systems containing the N-C-N fragment

被引:19
|
作者
Shevtsov, AV
Petukhova, VY
Strelenko, YA
Lyssenko, KA
Makhova, NN
Tartakovsky, VA
机构
[1] Russian Acad Sci, ND Zelinskii Organ Chem Inst, Moscow 119991, Russia
[2] Russian Acad Sci, AN Nesmeyanov Organoelement Cpds Inst, Moscow 119991, Russia
基金
俄罗斯基础研究基金会;
关键词
diaziridines; ketenes; imidazolidin-4-ones; alkenylacetamides; beta-lactams; X-ray diffraction analysis;
D O I
10.1007/s11172-005-0351-z
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The reaction of 1,2-dialkyldiaziridines with ketenes proceeds through the N-N bond cleavage to form three types of structures containing the N-C-N fragment, viz., 1,3-dialkylimidazolidin-4-ones, 3,5-diacyl-3,5-diazaliept-1-enes, and beta-lactams. The reaction pathway depends on the reaction conditions and the structures of the starting compounds.
引用
收藏
页码:1021 / 1031
页数:11
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