Divergent reactivity of α-oximino carbenoids: facile access to 2-isoxazolines and 2H-azirines

被引：39
|
作者：
Qi, Xinxin [1 ]
Jiang, Yaojia [1 ]
Park, Cheol-Min [1 ]
机构：
[1] Nanyang Technol Univ, Sch Phys & Math Sci, Div Chem & Biol Chem, Singapore 637371, Singapore
来源：
CHEMICAL COMMUNICATIONS | 2011年 / 47卷 / 27期
关键词：
C-H FUNCTIONALIZATION; ASYMMETRIC-SYNTHESIS; VINYL AZIDES; INSERTION; PYRROLES; ESTERS;
D O I：
10.1039/c1cc11683e
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Mild catalytic reaction conditions for the synthesis of 2-isoxazolines and 2H-azirines have been developed via carbenoids derived from alpha-oximino diazo compounds. This has been utilized in the one-pot synthesis of pyrroles in the presence of 1,3-dicarbonyl compounds.
引用
收藏
页码：7848 / 7850
页数：3
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