Density of hydrous carbonate melts under pressure, compressibility of volatiles and implications for carbonate melt mobility in the upper mantle

Knowledge of the effect of water on the density of carbonate melts is fundamental to constrain their mobility in the Earth's interior and the exchanges of carbon between deep and surficial reservoirs. Here we determine the density of hydrous MgCO3 and CaMg(CO3)(2) melts (10 wt% H2O) from 1.09 to 2.98 GPa and 1111 to 1763 K by the X-ray absorption method in a Paris-Edinburgh press and report the first equations of state for hydrous carbonate melts at high pressure. Densities range from 2.26(3) to 2.50(3) g/cm(3) and from 2.34(3) to 2.48(3) g/cm(3) for hydrous MgCO3 and CaMg(CO3)(2) melts, respectively. Combining the results with density data for the dry counterparts from classical Molecular Dynamic (MD) simulations, we derive the partial molar volume ((V) over bar (H2O), (V) over bar (CO2)) and compressibility of H2O and CO2 components at crustal and upper mantle conditions. Our results show that (V) over bar (CO2) in alkaline carbonate melts is larger and less compressible than (V) over bar (H2O) at the investigated conditions. Neither the compressibility nor (V) over bar (H2O) depend on carbonate melt composition within uncertainties, but they are larger than those in silicate melts at crustal conditions. (V) over bar (H2O) in alkaline earth carbonate melts decreases from 25(1) to 16.5(5) cm(3)/mol between 0.5 and 4 GPa at 1500 K. Contrastingly, comparison of our results with literature data suggests strong compositional effects on (V) over bar (CO2), that is also less compressible than in transitional melts (e.g., kimberlites) and carbonated basalts. We further quantify the effect of hydration on the mobility of carbonate melts in the upper mantle and demonstrate that 10 wt% H2O increases the mobility of MgCO3 melts from 37 to 67 g.cm(-3).Pa(-1)s(-1) at 120 km depth. These results suggest efficient carbonate melt extraction during partial melting and fast migration of incipient melts in the shallow upper mantle. (C) 2019 Elsevier B.V. All rights reserved.