Effect of reactive diluents on properties of unsaturated polyester/montmorillonite nanocomposites

被引:23
|
作者
Kim, HG [1 ]
Oh, DH [1 ]
Lee, HB [1 ]
Min, KE [1 ]
机构
[1] Kyungpook Natl Univ, Dept Polymer Sci, Taegu 702701, South Korea
关键词
unsaturated polyester; montmorillonite; nanocomposites; diluent effect; reactive processing;
D O I
10.1002/app.13657
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Unsaturated polyester (UP)/montmorillonite (MMT) nanocomposite was prepared by using hydroxypropylacrylate (HPA) as a reactive diluent instead of conventional styrene monomer and the effect of polarity of reactive diluent on properties of nanocomposite was investigated. X-ray and mechanical test data indicated that mixing for an extended period of time is essential to enhance the physical properties of nanocomposites in the UP/Cloisite 6A system. This was attributed to the high polarity of HPA that may disturb the preintercalation of UP resin into the galleries of MMT. (C) 2004 Wiley Periodicals, Inc.
引用
收藏
页码:238 / 242
页数:5
相关论文
共 50 条
  • [1] Effect of sonication and clay content on the properties of unsaturated polyester/montmorillonite nanocomposites
    Romanzini, Daiane
    Silva, Adriana A.
    Soares, Bluma G.
    Zattera, Ademir J.
    Amico, Sandro C.
    [J]. JOURNAL OF COMPOSITE MATERIALS, 2017, 51 (02) : 187 - 197
  • [2] Nanocomposites based on montmorillonite and unsaturated polyester
    Kornmann, X
    Berglund, LA
    Sterte, J
    [J]. POLYMER ENGINEERING AND SCIENCE, 1998, 38 (08): : 1351 - 1358
  • [3] Preparation, structure and properties of unsaturated polyester/modified montmorillonite nanocomposites
    Zhou, Y
    Yang, XY
    Jia, DM
    [J]. JOURNAL OF POLYMER MATERIALS, 2005, 22 (01): : 61 - 67
  • [4] Effect of clay silylation on curing and mechanical and thermal properties of unsaturated polyester/montmorillonite nanocomposites
    Romanzini, Daiane
    Frache, Alberto
    Zattera, Ademir J.
    Amico, Sandro C.
    [J]. JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 2015, 87 : 9 - 15
  • [5] Effect of POSS-Modified Montmorillonite on Thermal, Mechanical, and Electrical Properties of Unsaturated Polyester Nanocomposites
    Divakaran, Nidhin
    Kale, Manoj B.
    Dhamodharan, Duraisami
    Mubarak, Suhail
    Wu, Lixin
    Wang, Jianlei
    [J]. POLYMERS, 2020, 12 (09)
  • [6] Cure behavior of unsaturated polyester/modified montmorillonite nanocomposites
    Zhou, Yan
    Yang, Xiaoyun
    Jia, Demin
    [J]. POLYMER INTERNATIONAL, 2007, 56 (02) : 267 - 274
  • [7] Preparation and Characterization of Unsaturated Polyester/Organic Montmorillonite Nanocomposites
    Tsai, Tsung-Yen
    Chen, Wen-Chi
    Zhou, Guan-Ren
    Shiu, Wei-Chuan
    [J]. MATERIALS RESEARCH AND APPLICATIONS, PTS 1-3, 2014, 875-877 : 150 - 154
  • [8] Unsaturated polyester/montmorillonite nanocomposites with improved mechanical and thermal properties fabricated by in situ polymerization
    Wu, Shan
    Wang, Lei
    Wu, Lixin
    Weng, Zixiang
    Zhou, Yu
    [J]. JOURNAL OF APPLIED POLYMER SCIENCE, 2017, 134 (35)
  • [9] Effect of Ammonium Polyphosphate on Flame Retardancy, Thermal Stability, and Mechanical Properties of Unsaturated Polyester/Phenolic/Montmorillonite Nanocomposites
    Hassan, Azman
    Hau, Lee Yong
    Hasan, Mahbub
    [J]. ADVANCES IN POLYMER TECHNOLOGY, 2017, 36 (03) : 278 - 283
  • [10] Volume shrinkage characteristics for unsaturated polyester-montmorillonite nanocomposites
    Huang, YJ
    Guo, TJ
    Liaw, WD
    Lin, YT
    Chen, UJ
    Tseng, GD
    [J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2005, 230 : U3742 - U3742