Preferential oxidation of CO in H2-Rich gas at low temperatures over Au nanoparticles supported on metal oxides

被引:31
|
作者
Imai, Hiroyuki [1 ,2 ]
Date, Masakazu [1 ]
Tsubota, Susumu [1 ,3 ]
机构
[1] Natl Inst Adv Ind Sci & Technol, Res Inst Innovat Sustainable Chem, Tsukuba, Ibaraki 3058569, Japan
[2] Hokkaido Univ, Grad Sch Environm Sci, Sapporo, Hokkaido 0600810, Japan
[3] Natl Inst Adv Ind Sci & Technol, Collaborat Promot Dept, Ikeda, Osaka 5638577, Japan
关键词
Au catalyst; CO oxidation; PROX; Au loading amount; support effect; low temperature;
D O I
10.1007/s10562-008-9501-x
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
We investigated Au catalysts supported on TiO2, Fe2O3, and ZnO for their preferential oxidation of CO in a H-2-rich atmosphere. Both full conversion and selectivity were achieved over Au/Fe2O3 and Au/ZnO around room temperature, but at higher temperatures the CO conversion was suppressed due to competition between CO and H-2.
引用
收藏
页码:68 / 73
页数:6
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