Selective reduction of allenyl(diphenyl)phosphine oxides to allyl(diphenyl)phosphine oxides

被引：1
|
作者：
Lozovskiy, S. V. [1 ]
Aleksandrova, M. I. [1 ]
Vasilyev, A. V. [1 ,2 ]
机构：
[1] St Petersburg State Univ, Univ Skii Pr 26, St Petersburg 198504, Russia
[2] St Petersburg Forest Tech Univ, Inst Skii Per 5, St Petersburg 194021, Russia
来源：
RUSSIAN JOURNAL OF ORGANIC CHEMISTRY | 2017年 / 53卷 / 07期
关键词：
ACID-PROMOTED TRANSFORMATIONS; 1,4-DIHYDROPHOSPHINOLINE 1-OXIDES; INTERMOLECULAR HYDROPHOSPHINATION; ALLENES; CYCLIZATION; ROUTE; ALKYNES;
D O I：
10.1134/S1070428017070065
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The reduction of allenyl(diphenyl)phosphine oxides with HSiCl3 or LiAlH4 selectively afforded the corresponding allyl(diphenyl)phosphine oxides. 3-Methylbut-2-en-1-yl(diphenyl)phosphine oxide reacted with AlCl3 to give a mixture of 4,4-dimethyl-1-phenyl-1,2,3,4-tetrahydro-lambda(5)-phosphinoline 1-oxide and 4,4-dimethyl-1-phenyl-1,4-dihydro-lambda(5)-phosphinoline 1-oxide.
引用
收藏
页码：995 / 998
页数：4
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