Syntheses and molecular structures of ruthenium complexes with dithiophosphate ligands

被引：21
|
作者：
Liu, XA
Zhang, QF [1 ]
Leung, WH
机构：
[1] Anhui Univ Technol, Dept Chem & Chem Engn, Maanshan 243002, Anhui, Peoples R China
[2] Hong Kong Univ Sci & Technol, Dept Chem, Kowloon, Hong Kong, Peoples R China
来源：
JOURNAL OF COORDINATION CHEMISTRY | 2005年 / 58卷 / 15期
基金：
中国国家自然科学基金;
关键词：
ruthenium; sulfur; synthesis; crystal structure; dithiophosphate;
D O I：
10.1080/00958970500174061
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Reactions of [Ru(PPh3)(3)Cl-2] and [RuHCl(CO)(PPh3)(3)] with K[S2P(OEt)(2)] in THF afforded [Ru{S2P(OEt)(2)}(2)(PPh3)(2)] ( 1) and [RuH(CO){S2P(OEt)(2)}(PPh3)(2)] (2), respectively. The crystal structures of complexes 1 and 2 have been determined by X-ray crystallography. The ruthenium atom in both molecules of 1 and 2 adopt an octahedral configuration. The average Ru - P and Ru - S distances in 1 are 2.3324(10) and 2.4974(11) angstrom, respectively. The corresponding bond lengths for 2 are 2.3551(9) and 2.5474(11) angstrom.
引用
收藏
页码：1299 / 1305
页数：7
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