Synthesis and properties of 4,4,5,5-tetrafluoro-3-trifluoromethyl-1,3-oxazolidin-2-one

被引：2
|
作者：
Juschke, R [1 ]
Hasel, P [1 ]
Sartori, P [1 ]
机构：
[1] Univ Duisburg Gesamthsch, Fachbereich 6, D-47048 Duisburg, Germany
来源：
JOURNAL OF FLUORINE CHEMISTRY | 1998年 / 90卷 / 01期
关键词：
electrochemical fluorination (ECF); 3-methyl-1,3-oxazolidin-2-one; 4,4,5,5-tetrafluoro-3-trifluoromethyl-1,3-oxazolidin-2-one;
D O I：
10.1016/S0022-1139(98)00162-6
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The electrochemical fluorination (ECF) of 3-methyl-1,3-oxazolidin-2-one (1) in anhydrous HF leads to the hitherto unknown 3,4,5,5-tetrafluoro-3-trifluoromethyl- 1,3-oxazolidin-2-one (4) in 14% yield. Spectral data (C-13-NMR, F-19-NMR, IR and mass spectra) were recorded and other physical properties (viscosity, melting point, boiling point and density) were determined. In addition the oxidation and reduction stability was measured using cyclic voltammetry (CV). (C) 1998 Elsevier Science S.A. All rights reserved.
引用
收藏
页码：77 / 80
页数：4
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