The bond valence method - Applied to complex thioanions and heterobimetallic complexes of copper with molybdenum and tungsten via bridging sulfur ligands

被引：1

作者：

Boller, H ^{[1
]}

机构：

[1] Johannes Kepler Univ, Inst Chem, A-4040 Linz, Austria

来源：

APPLIED CRYSTALLOGRAPHY | 2001年

关键词：

D O I：

10.1142/9789812811325_0004

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

By applying the bond valence model to complex thioanions [TOnS4-n](2-) (T = Mo W), thiocuprate anions [CuS](-) and [Cu2S3](4-) as well as some heterobimetallic cluster anions of these metals it is shown that interesting information on the bonding and charge distribution in these compounds can be obtained by very simple calculations.

引用

页码：27 / 29

页数：3

共 4 条

[1] Synthesis and structural characterization of copper-molybdenum-sulfur and copper-tungsten-sulfur cluster complexes (n-Bu4N)[OMS3Cu3Br2L2] with heterocyclic thiones as ligands
Beheshti, Azizolla
Clegg, William
Dale, Sophie H.
Solimankhani, Ahmad
POLYHEDRON, 2008, 27 (02) : 777 - 782
[2] Syntheses, structures, and reactivity of dinuclear molybdenum-platinum and tungsten-platinum complexes with bridging carbonyl, sulfur dioxide, isonitrile, and aminocarbyne ligands and a dppa backbone (dppa = Ph2PNHPPh2)
Knorr, M
Strohmann, C
ORGANOMETALLICS, 1999, 18 (02) : 248 - 257
[3] THE FIRST BINUCLEAR MOLYBDENUM AND TUNGSTEN COMPLEXES WITH DOUBLY-BRIDGING PYRIDINE-2-THIOLATO LIGANDS.X-RAY CRYSTAL STRUCTURE OF THE COMPLEX[Mo2（CO）4（μ-pyS）2（PPh3）2].2C7H8
You Mao SHI
Shi Wei LU
He Fu GUO
Ning Hai HU a.Dalian Institute of Chemical Physics
Chinese Chemical Letters, 1992, (09) : 741 - 742
[4] HOMOBIMETALLIC AND HETEROBIMETALLIC, MIXED-VALENCE M(II)/M(0) COMPLEXES OF MOLYBDENUM AND TUNGSTEN WITH S2CPR3 LIGANDS - X-RAY STRUCTURE OF [(ETA(3)-C3H5)(CO)2MO(MU-BR)(MU-S2CPCY3)MO(CO)3]
MIGUEL, D
PEREZMARTINEZ, JA
RIERA, V
GARCIAGRANDA, S
ORGANOMETALLICS, 1994, 13 (04) : 1336 - 1340

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