Elaboration, Structural, Vibrational, DSC Investigations and Hirshfeld Surface Analysis of New Organic-Inorganic Hybrid Compound: [H2mela]Cu2Br6

The present paper accounts for the synthesis, crystal structure, differential scanning calorimetry and vibrational spectroscopy of a new compound (1,3,5-triazinidium-2,4,6-triamine) hexabromidodicuprate (II) grown at room temperature by slow evaporation of aqueous solution. From X-ray diffraction data collected at room temperature, it is concluded that it crystallizes in the monoclinic system (P2(1)/c space group). The anion and the cation are linked by N-H center dot center dot center dot Br hydrogen bonds. Furthermore, the room temperature IR and Raman spectra of the title compound were recorded and analyzed. The differential scanning calorimetric has also been investigated. Hirshfeld surfaces were used to confirm the existence of inter-molecular interactions in the compound.