Inorganic-organic hybrids derived from oxovanadium sulfate motifs:: synthesis and characterization of [VIVO( μ3-SO4)(2,2′-bpy)]∞

被引：48
|
作者：
Khan, MI [1 ]
Cevik, S
Doedens, RJ
机构：
[1] IIT, Dept Biol Chem & Phys Sci, Chicago, IL 60616 USA
[2] Univ Calif Irvine, Dept Chem, Irvine, CA 92697 USA
来源：
CHEMICAL COMMUNICATIONS | 2001年 / 19期
关键词：
D O I：
10.1039/b106866k
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The hydrothermal reaction of V2O5, V2O3, 2,2'-bpy and Na2SO4 in dilute sulfuric acid yields a novel hybrid, [(VO)-O-IV(mu (3)-SO4)(2,2'-bpy)]proportional to, which demonstrates the potential of constructing a new class of robust composite solids composed of a {V/O/SO4}-based framework decorated with organic functionalities by combining appropriate vanadyl sulfate motifs with a variety of organic ligands.
引用
收藏
页码：1930 / 1931
页数：2
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