Rapid and selective oxidation of benzyl alcohols to aldehydes and ketones with novel vanadium polyoxometalate under solvent-free conditions

被引：33
|
作者：
Dewan, Anindita [2 ]
Sarma, Tridib [2 ,3 ]
Bora, Utpal [1 ]
Kakati, Dilip K. [2 ]
机构：
[1] Dibrugarh Univ, Dept Chem, Dibrugarh 786004, Assam, India
[2] Gauhati Univ, Dept Chem, Gauhati 781014, Assam, India
[3] Univ Hyderabad, Sch Chem, Hyderabad 500046, Andhra Pradesh, India
来源：
TETRAHEDRON LETTERS | 2011年 / 52卷 / 20期
关键词：
Polyoxometalate; Oxidation; Benzylic alcohol; Solvent-free; Vanadium; CATALYZED AEROBIC OXIDATION; HETEROPOLY COMPOUNDS; EFFICIENT; SYSTEMS; OXYGEN; ACIDS;
D O I：
10.1016/j.tetlet.2011.03.044
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A novel vanadium polyoxometalate [(C6H5CH2)(CH3)(3)N](3)[H3V10O28]3H(2)O works as a useful oxidant for selective and rapid oxidation of benzylic alcohols to the corresponding carbonyl compounds in the presence of PTSA under solvent-free, room temperature in excellent yield. (C) 2011 Elsevier Ltd. All rights reserved.
引用
收藏
页码：2563 / 2565
页数：3
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