Synthesis, crystal structure and photocatalytic properties of a Mn (II) metal-organic framework based on a thiophene-functionalized dicarboxylate ligand

被引：13

作者：

Fang, Xiao-Dan ^{[1
]}

Yang, Li-Bo ^{[1
]}

Dou, Ai-Na ^{[1
]}

Liu, Yan-E ^{[1
]}

Yao, Jun ^{[1
]}

Xu, Quan-Qing ^{[1
]}

Zhu, Ai-Xin ^{[1
]}

机构：

[1] Yunnan Normal Univ, Fac Chem & Chem Engn, Kunming 650500, Yunnan, Peoples R China

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2018年 / 96卷

基金：

中国国家自然科学基金;

关键词：

Metal-organic framework; Thiophene-functionalized dicarboxylate; lvt topology; Photocatalytic property; VISIBLE-LIGHT IRRADIATION; DONOR CO-LIGANDS; MAGNETIC-PROPERTIES; DEGRADATION; DYE; LUMINESCENT; REMOVAL; DESIGN; THIOPHENE-2,5-DICARBOXYLATE; POLLUTANTS;

D O I：

10.1016/j.inoche.2018.08.017

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A novel metal-organic framework formulated as [Mn(DMTDC)(DMF)] (1) was synthesized under solvothermal conditions by using a thiophene-functionalized dicarboxylate ligand, 3,4-dimethylthieno[2,3-b]thiophene-2,5-dicarboxylic acid (H2DMTDC), which displays a uninodal, 4-connected lvt net. After the removal of coordinated DMF, this framework displays permanent porosity and excellent photocatalytic activity for methylene blue (MB) dye degradation in aqueous solution under UV light.

引用

页码：124 / 127

页数：4

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