Direct and site-selective Pd(II)-catalyzed C-7 arylation of indolines with arylsilanes

被引：29

作者：

Luo, Haiqing ^{[1
]}

Liu, Haidong ^{[1
]}

Zhang, Zhipeng ^{[1
]}

Xiao, Yifan ^{[1
]}

Wang, Sihui ^{[1
]}

Luo, Xuzhong ^{[1
]}

Wang, Kejun ^{[1
]}

机构：

[1] Gannan Normal Univ, Dept Chem & Chem Engn, Ganzhou 341000, Peoples R China

来源：

RSC ADVANCES | 2016年 / 6卷 / 45期

关键词：

CROSS-COUPLING REACTIONS; C-H ARYLATION; ORGANOSILICON REAGENTS; 7-SUBSTITUTED INDOLES; ROOM-TEMPERATURE; BOND ACTIVATION; PALLADIUM; FUNCTIONALIZATION; ALKENYLATION; ALKYNYLATION;

D O I：

10.1039/c6ra06915k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The palladium-catalyzed oxidative arylation of indolines with arylsilanes at the C-7 position via C-H bond activation has been reported. This transformation has been applied to a wide range of substrates. It represents a facile access to C-7 arylated indolines, which can be conveniently transformed into C-7 arylated indoles.

引用

页码：39292 / 39295

页数：4

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