Bis{2,6-bis[3-(2,4,6-trimethylphenyl)-pyrazol-1-yl-κN2]pyridine-κN}zinc(II) diperchlorate bis(nitromethane) solvate

被引：13
|
作者：
Halcrow, MA [1 ]
Kilner, CA [1 ]
Thornton-Pett, M [1 ]
机构：
[1] Univ Leeds, Sch Chem, Leeds LS2 9JT, W Yorkshire, England
来源：
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 2000年 / 56卷 / 12期
关键词：
D O I：
10.1107/S0108270100012981
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The title compound, [Zn(C29H29N5)(2)](ClO4)(2). 2CH(3)NO(2), contains a Zn-II ion showing only small deviations from local D-2d symmetry. The lower rhombicity exhibited by this complex compared with that of its Cu-II congener suggests that the highly rhombic stereochemistry exhibited by the latter is largely imposed by the stereoelectronic preferences of the Cu-II ion.
引用
收藏
页码：1425 / 1426
页数：2
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