Sm/HOAc/EtOH system-mediated reduction of Baylis-Hillman acetates

被引：6
|
作者：
Liu, Yunkui [1 ]
Mao, Daffie [1 ]
Xu, Danqian [1 ]
Xu, Zhenyuan [1 ]
Zhang, Yongmin [2 ]
机构：
[1] Zhejiang Univ Technol, State Key Lab Breeding Base Green Chem Synth Tech, Hangzhou 310014, Peoples R China
[2] Zhejiang Univ, Dept Chem, Hangzhou 310027, Peoples R China
来源：
SYNTHETIC COMMUNICATIONS | 2007年 / 37卷 / 22-24期
关键词：
Baylis-Hillman acetates; (2E)-2-methylalk-2-enoates; 2-methyl alkanoates; selective; Sm/HOAc/EtOH system;
D O I：
10.1080/00397910701577570
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Selective formation of (2E)-2-methylalk-2-enoates or 2-methyl alkanoates could be achieved in moderate to good yields under mild conditions via Sm/HOAc/EtOH system-mediated reduction of Baylis-Hillman acetates depending on the amount of samariurn consumed in the reactions.
引用
收藏
页码：4389 / 4397
页数：9
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