Palladium(II) extraction with 1-{[2-(2,4-Dichlorophenyl)-4-propyl-1,3-dioxolan-2-yl]-methyl}-1H-1,2,4-triazole from nitric acid solutions

被引：2

作者：

Khisamutdinov, R. A. ^{[1
]}

Anpilogova, G. R. ^{[1
]}

Murinov, Yu. I. ^{[1
]}

Spirikhin, L. V. ^{[1
]}

机构：

[1] Russian Acad Sci, Inst Organ Chem, Ufa Sci Ctr, Ufa 450054, Russia

来源：

RUSSIAN JOURNAL OF INORGANIC CHEMISTRY | 2010年 / 55卷 / 12期

关键词：

COMPLEXES; 1,2,4-TRIAZOLE; DERIVATIVES; SPECTRA;

D O I：

10.1134/S0036023610120284

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Palladium(II) extraction from nitric acid solutions with 1-{[2-(2,4-dichlorophenyl)-4-propyl-1,3-dioxolan-2-yl]-methyl}-1H-1,2,4-triazole in toluene is studied. The reagent efficiently extracts palladium(II) from 0.2-6 M HNO3 by a coordination mechanism yielding the complex Pd-2(NO3)(4) S (3) in the organic phase. The reagent can be used for selective separation of palladium(II) from nickel(II), copper(II), and iron(III) in the specified aqueous phase acidity range.

引用

页码：1992 / 1997

页数：6

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[1] Palladium(II) extraction with 1-{[2-(2,4-Dichlorophenyl)-4-propyl-1,3-dioxolan-2-yl]-methyl}-1H-1,2,4-triazole from nitric acid solutions
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G. R. Anpilogova
Yu. I. Murinov
L. V. Spirikhin
Russian Journal of Inorganic Chemistry, 2010, 55 : 1992 - 1997
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