This work reports on an analysis of the chemical composition, structural, and optical properties of Mg-doped zinc oxide (ZMO) thin films with Mg concentration up to 54 at. % and prepared by the spray pyrolysis technique from acetate precursors. Chemical analysis show that the [Mg]/[Zn] ratio incorporated into the films is higher than that present in the starting solution. X-ray diffraction, Raman scattering, and transmission measurements show that all samples exhibit a single phase wurtzite structure with a transmittance above 70% in the visible range. Increasing Mg content leads to an increase of the band gap energy from 3.23 in pure ZnO to 3.57 eV in films with 54 at % of Mg content. (C) 2010 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
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College of Information Engineering, Hebei University of Technology, Tianjin 300130, China
Key Laboratory of Photo-electronic Information Science and Technology Min. of Edu., Institute of Photo-electronic Thin Film Device and Technique, Nankai University, Tianjin 300071, ChinaCollege of Information Engineering, Hebei University of Technology, Tianjin 300130, China
Bian, Nan
Zhang, Xiao-Dan
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Key Laboratory of Photo-electronic Information Science and Technology Min. of Edu., Institute of Photo-electronic Thin Film Device and Technique, Nankai University, Tianjin 300071, ChinaCollege of Information Engineering, Hebei University of Technology, Tianjin 300130, China
Zhang, Xiao-Dan
Zhang, Xia
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College of Information Engineering, Hebei University of Technology, Tianjin 300130, China
Key Laboratory of Photo-electronic Information Science and Technology Min. of Edu., Institute of Photo-electronic Thin Film Device and Technique, Nankai University, Tianjin 300071, ChinaCollege of Information Engineering, Hebei University of Technology, Tianjin 300130, China
Zhang, Xia
Zhao, Ying
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Key Laboratory of Photo-electronic Information Science and Technology Min. of Edu., Institute of Photo-electronic Thin Film Device and Technique, Nankai University, Tianjin 300071, ChinaCollege of Information Engineering, Hebei University of Technology, Tianjin 300130, China
Zhao, Ying
Yang, Rui-Xia
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College of Information Engineering, Hebei University of Technology, Tianjin 300130, ChinaCollege of Information Engineering, Hebei University of Technology, Tianjin 300130, China
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Yonsei Univ, Dept Mat Sci & Engn, Informat & Elect Mat Res Lab, Seoul 120749, South KoreaYonsei Univ, Dept Mat Sci & Engn, Informat & Elect Mat Res Lab, Seoul 120749, South Korea
Hwang, DK
Jeong, MC
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Yonsei Univ, Dept Mat Sci & Engn, Informat & Elect Mat Res Lab, Seoul 120749, South KoreaYonsei Univ, Dept Mat Sci & Engn, Informat & Elect Mat Res Lab, Seoul 120749, South Korea
Jeong, MC
Myoung, JM
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Yonsei Univ, Dept Mat Sci & Engn, Informat & Elect Mat Res Lab, Seoul 120749, South KoreaYonsei Univ, Dept Mat Sci & Engn, Informat & Elect Mat Res Lab, Seoul 120749, South Korea