Zn1-xMgxO thin films deposited by spray pyrolysis

被引:10
|
作者
Sahal, M. [1 ]
Mari, B. [1 ]
Mollar, M. [1 ]
Manjon, F. J. [1 ]
机构
[1] Univ Politecn Valencia, Dept Fis Aplicada, Inst Disseny Fabricacio Automatitzada IDF, Valencia 46022, Spain
关键词
ZnMgO; spray pyrolysis; doping; structure; optical properties; band gap; OPTICAL-PROPERTIES; BAND-GAP; ZNO; MGXZN1-XO; GROWTH; AL;
D O I
10.1002/pssc.200983751
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
This work reports on an analysis of the chemical composition, structural, and optical properties of Mg-doped zinc oxide (ZMO) thin films with Mg concentration up to 54 at. % and prepared by the spray pyrolysis technique from acetate precursors. Chemical analysis show that the [Mg]/[Zn] ratio incorporated into the films is higher than that present in the starting solution. X-ray diffraction, Raman scattering, and transmission measurements show that all samples exhibit a single phase wurtzite structure with a transmittance above 70% in the visible range. Increasing Mg content leads to an increase of the band gap energy from 3.23 in pure ZnO to 3.57 eV in films with 54 at % of Mg content. (C) 2010 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
引用
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页数:5
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