Effect of surface modified kaolin on properties of polypropylene grafted maleic anhydride

被引:32
|
作者
Yang, Ni [1 ]
Zhang, Zuo-Cai [1 ]
Ma, Ning [1 ]
Liu, Huan-Li [1 ]
Zhan, Xue-Qing [1 ]
Li, Bing [1 ]
Gao, Wei [1 ]
Tsai, Fang-Chang [1 ]
Jiang, Tao [1 ]
Chang, Chang-Jung [2 ]
Chiang, Tai-Chin [3 ]
Shi, Dean [1 ]
机构
[1] Hubei Univ, Hubei Collaborat Innovat Ctr Adv Organ Chem Mat, Sch Mat Sci & Engn,Minist Educ, Hubei Key Lab Polymer Mat Key Lab Green Preparat, Wuhan 430062, Hubei, Peoples R China
[2] Ind Technol Res Inst, Mat & Chem Res Labs, Hsinchu, Taiwan
[3] Natl Taiwan Univ Sci & Technol, Dept Mat Sci & Engn, Taipei, Taiwan
关键词
PP-g-MAH; Kaolin; Modification; Thermal stability; FLAME-RETARDANT POLYPROPYLENE; AMMONIUM POLYPHOSPHATE; COMPOSITES; MECHANISM; FUNCTIONALIZATION;
D O I
10.1016/j.rinp.2017.02.030
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
To achieve reinforcement of mechanical and thermal performances of polypropylene (PP) product, this work aimed at fabrication of surface modified kaolin (M-kaolin) filled polypropylene grafted maleic anhydride (PP-g-MAH) composites with varying contents of fillers and investigation of their mechanical and thermal properties. And the prepared PP-g-MAH/M-kaolin composites were characterized by means of Fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM) and thermogravimetric analysis (TGA). Fracture analysis by SEM showed M-kaolin particles were well dispersed in the PP-g-MAH matrix. Mechanical behaviors were determined by tensile strength, tensile strain at break and impact strength analysis. Impact strength of PP-g-MAH/2 wt% M-kaolin composites was improved up to 30% comparing with unfilled composites. Thermostability had been found enhanced when Mkaolin added. The results revealed PP-g-MAH/M-kaolin composites showed the optimal thermal and mechanical properties when 2 wt% of M-kaolin was added. (C) 2017 The Authors. Published by Elsevier B. V. This is an open access article under the CC BY-NC-ND license.
引用
收藏
页码:969 / 974
页数:6
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