Rich C-H bond activations of yttrium alkyl complexes bearing phosphinimino-amine ligands

被引：14
|
作者：
Li, Danfeng [1 ,2 ]
Li, Shihui [1 ,2 ]
Cui, Dongmei [1 ]
Zhang, Xuequan [1 ]
机构：
[1] Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China
[2] Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China
来源：
JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2010年 / 695卷 / 25-26期
基金：
中国国家自然科学基金;
关键词：
C-H bond activation; Yttrium alkyl complex; Phosphinimino-amine; Polymerization; BETA-DIKETIMINATO LIGANDS; RARE-EARTH-METALS; STRUCTURAL-CHARACTERIZATION; CATALYTIC-ACTIVITY; LANTHANIDE COMPLEXES; CYCLOOCTATETRAENE COMPLEXES; DIALKYLSCANDIUM COMPLEXES; POLYMERIZATION CATALYSTS; ORGANOYTTRIUM COMPLEXES; HYDRIDE COMPLEXES;
D O I：
10.1016/j.jorganchem.2010.09.005
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Aseries of phosphinimino-amine compounds (2,6-iPr(2)-C6H3NH)C(Me)CHPPh2(NAr)(Ar = 2,6-iPr(2)-C6H3 (HL1),2,6-Et-2-C6H3 (HL2),2,6-Me-2-C6H3 (HL3), C6H5 (HL4), 3-CF3-C6H4 (HL5)) that existed in imine and amine forms were synthesized and fully characterized. Treatment of HL1-5 with Y(CH2SiMe3)(3)(THF)(2) afforded the corresponding yttrium mono- or bis(alkyl) complexes that depended significantly on the ancillary ligands. The reactions between HL1-3 and Y(CH2SiMe3)(3)(THF)(2) at room temperature generated mononuclear monoalkyl complexes 1-3 via deprotonation and C-H bond activation. However, when compounds HL4,5 were used, the dialkyl complexes 4 and 5 were isolated by deprotonation only. The molecular structures of complexes 1-4 were characterized with X-ray crystallography and discussed. (c) 2010 Elsevier B.V. All rights reserved.
引用
下载
收藏
页码：2781 / 2788
页数：8
相关论文
共 50 条
  • [1] Half-metallocene complexes of yttrium with amidinate ligands: Monoalkyl yttrium formation and C-H bond activation
    Xu, Tie-Qi
    Liu, Jun-Hu
    Liu, Yong
    POLYHEDRON, 2016, 113 : 50 - 54
  • [2] Concurrent N-H, C-H bond activations
    不详
    CHEMICAL & ENGINEERING NEWS, 2006, 84 (48) : 25 - 25
  • [3] C-H Bond Activations by Metal Oxo Compounds
    Gunay, Ahmet
    Theopold, Klaus H.
    CHEMICAL REVIEWS, 2010, 110 (02) : 1060 - 1081
  • [4] C-H bond activations by new labile η6-arene complexes of iridium
    Torres, F
    Sola, E
    Martín, M
    López, JA
    Lahoz, FJ
    Oro, LA
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (45) : 10632 - 10633
  • [5] C-H Bond Activations by Monoanionic, PNP-Supported Scandium Dialkyl Complexes
    Levine, Daniel S.
    Tilley, T. Don
    Andersen, Richard A.
    ORGANOMETALLICS, 2015, 34 (19) : 4647 - 4655
  • [6] C-H AND C-C BOND ACTIVATIONS JOIN HANDS
    不详
    CHEMICAL & ENGINEERING NEWS, 2013, 91 (50) : 23 - 23
  • [7] C-H Bond Cleavage of Acetonitrile by Iridium Complexes Bearing PNP-Pincer-Type Phosphaalkene Ligands
    Chang, Yung-Hung
    Takeuchi, Katsuhiko
    Wakioka, Masayuki
    Ozawa, Fumiyuki
    ORGANOMETALLICS, 2015, 34 (10) : 1957 - 1962
  • [8] Multiple C-H Bond Activations in Corannulene by a Dirhenium Complex
    Adams, Richard D.
    Dhull, Poonam
    Pennachio, Matthew
    Petrukhina, Marina A.
    Smith, Mark D.
    CHEMISTRY-A EUROPEAN JOURNAL, 2019, 25 (16) : 4234 - 4239
  • [9] C-H BOND ACTIVATION OF ALKENECARBOXYLATES BY RUTHENIUM COMPLEXES HAVING TRIPHENYLPHOSPHINE LIGANDS
    KOMIYA, S
    AOKI, Y
    MIZUHO, Y
    OYASATO, N
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1993, 463 (1-2) : 179 - 185
  • [10] Alkene C-H activations at dinuclear complexes promoted by oxidation
    Jiménez, MV
    Sola, E
    Caballero, J
    Lahoz, FJ
    Oro, LA
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2002, 41 (07) : 1208 - +
12345