Development of chiral N,N-ditopic metalloligands based on a Cinchona alkaloids' backbone for constructing homochiral coordination polymers

被引：17

作者：

Lewinski, Janusz ^{[1
,2
]}

Kaczorowski, Tomasz ^{[1
,2
]}

Justyniak, Iwona ^{[2
]}

Prochowicz, Daniel ^{[1
]}

机构：

[1] Warsaw Univ Technol, Dept Chem, PL-00664 Warsaw, Poland

[2] Polish Acad Sci, Inst Phys Chem, PL-01224 Warsaw, Poland

来源：

CHEMICAL COMMUNICATIONS | 2011年 / 47卷 / 03期

关键词：

METAL-ORGANIC FRAMEWORKS; BUILDING-BLOCKS; LIGANDS; COMPLEXES; CATALYSIS; ORGANOALUMINUM; BIPYRIDINE; SEPARATION; MOLECULES;

D O I：

10.1039/c0cc03586f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The bimetallic chiral bipyridyl-type metalloligands based on aluminium derivatives of cinchonine, [R2Al(mu-CN)](2) (R = Me or Et), in combination with the corresponding ZnR2 compound as nodes were used for the generation of novel homochiral heterometallic coordination polymers of either zig-zag or helical topology, depending on the character of the R substituent.

引用

页码：950 / 952

页数：3

共 8 条

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