FTIR reflectance studies of electrochemically prepared polypyrrole films

被引:10
|
作者
Turcu, R
Brie, M
Leising, G
Tosa, V
Mihut, A
Niko, A
Bot, A
机构
[1] Inst Isotope & Mol Technol, R-3400 Cluj Napoca, Romania
[2] Inst Chem, Cluj Napoca 3400, Romania
[3] Graz Tech Univ, Inst Festkorperphys, A-8010 Graz, Austria
来源
关键词
D O I
10.1007/s003390050772
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Optical properties of polypyrrole (PPY) films electrochemically prepared in different conditions were investigated by FTIR reflectance spectroscopy in the range 200-6000 cm(-1). The effects of some relevant electrochemical parameters (the electrolyte, the polymerization current density, and the deposition time) on the reflectance spectra of polypyrrole are reported. The optical constants for polypyrrole films were calculated from the reflectance spectra by Kramers-Kronig technique. The decrease of the electropolymerization current density and film thickness results in an increase of the reflectance and de conductivity values for PPY(TSO).
引用
收藏
页码:283 / 287
页数:5
相关论文
共 50 条
  • [1] FTIR reflectance studies of electrochemically prepared polypyrrole films
    Turcu, R.
    Brie, M.
    Leising, G.
    Tosa, V.
    Mihut, A.
    Niko, A.
    Bot, A.
    Applied Physics A: Materials Science and Processing, 1998, 67 (03): : 283 - 287
  • [2] FTIR reflectance studies of electrochemically prepared polypyrrole films
    R. Turcu
    M. Brie
    G. Leising
    V. Tosa
    A. Mihut
    A. Niko
    A. Bot
    Applied Physics A, 1998, 67 : 283 - 287
  • [3] STUDIES ON ELECTROCHEMICALLY PREPARED OXIDIZED POLYPYRROLE SALT FILMS
    BI, XT
    YAO, YX
    WAN, MX
    WANG, P
    XIAO, K
    YANG, QY
    QIAN, RY
    MAKROMOLEKULARE CHEMIE-MACROMOLECULAR CHEMISTRY AND PHYSICS, 1985, 186 (05): : 1101 - 1108
  • [4] ESCA STUDIES OF ELECTROCHEMICALLY PREPARED POLYPYRROLE
    HAHN, SJ
    ZELLER, MV
    GAJDA, WJ
    JOURNAL OF ELECTRONIC MATERIALS, 1986, 15 (05) : 321 - 322
  • [5] Reflection and absorption studies on polypyrrole films electrochemically prepared with different electrolyte types
    Turcu, R
    Brie, M
    Leising, G
    Niko, A
    SYNTHETIC METALS, 1999, 100 (02) : 217 - 221
  • [6] Immobilization of glucose oxidase in electrochemically prepared polypyrrole films
    Natl Physical Lab, New Delhi, India
    J Mater Sci Lett, 2 (124-128):
  • [7] MECHANICAL-PROPERTIES OF ELECTROCHEMICALLY PREPARED POLYPYRROLE FILMS
    DIAZ, AF
    HALL, B
    IBM JOURNAL OF RESEARCH AND DEVELOPMENT, 1983, 27 (04) : 342 - 347
  • [8] CONDUCTIVITY AND ANISOTROPY OF ELECTROCHEMICALLY PREPARED CONDUCTING POLYPYRROLE FILMS
    SUN, BT
    JONES, JJ
    BURFORD, RP
    SKYLLAS-KAZACOS, M
    JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1989, 136 (03) : 698 - 701
  • [9] Immobilization of glucose oxidase in electrochemically prepared polypyrrole films
    Ramanathan, K
    Annapoorni, S
    Kumar, A
    Malhotra, BD
    JOURNAL OF MATERIALS SCIENCE LETTERS, 1996, 15 (02) : 124 - 128
  • [10] IMPROVEMENT IN THE QUALITY OF POLYPYRROLE FILMS PREPARED ELECTROCHEMICALLY ON A MERCURY ANODE
    BRADNER, FP
    SHAPIRO, JS
    SYNTHETIC METALS, 1988, 26 (01) : 69 - 77