The Cerium-Zirconium Binary Oxide as an Efficient Catalyst for Oxidation of α-Methylstyrene Oxide into Atrolactic Acid

被引：1

作者：

Huang, Benhua ^{[1
]}

Gao, Ruixia ^{[1
]}

Pan, Cheng ^{[1
]}

Fan, Chao ^{[1
]}

Jia, Xin ^{[1
]}

Pan, Wanli ^{[1
]}

Li, Xiaoyong ^{[1
]}

Li, Heng ^{[2
]}

Sun, Yang ^{[1
]}

Zhang, Donghua ^{[2
]}

机构：

[1] Xi An Jiao Tong Univ, Sch Sci, Dept Appl Chem, 28 Xianning West Rd, Xian 710049, Peoples R China

[2] Xian Technol Univ, Sch Mat & Chem Engn, 2 Xuefu Rd, Xian 710021, Peoples R China

来源：

CATALYSIS LETTERS | 2020年 / 150卷 / 09期

关键词：

Atrolactic acid; Ce-Zr binary oxide; alpha-Methylstyrene oxide; Oxidation; Catalyst; OXYGEN; ACETOPHENONE; REACTIVITY; CARBON;

D O I：

10.1007/s10562-020-03161-8

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The atrolactic acid is an important intermediate for synthesis of non-steroidal anti-inflammatory pharmaceuticals, and meanwhile the traditional synthesis of atrolactic acid demands harsh conditions, lengthy steps, or big power consumption. In order to overcome these drawbacks, a series of Ce-Zr binary oxides are first developed as catalysts for oxidation of alpha-methylstyrene oxide into atrolactic acid. Catalytic results reveal these catalysts have high activity and recycling potential. This work shows a new method for preparation of atrolactic acid, which could be carried out under benign conditions, providing satisfactory outputs.

引用

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页码：2607 / 2616

页数：10

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