CuX2-mediated halogenation of alkylidenecyclopropanes:: A highly efficient and stereoselective method for the preparation of Z-2,4-dihalobutenes

被引：36
|
作者：
Zhou, HW
Huang, M
Chen, WL
机构：
[1] Zhejiang Univ, Dept Chem, Hangzhou 310027, Peoples R China
[2] Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Oganomet Chem, Shanghai 200032, Peoples R China
来源：
SYNLETT | 2003年 / 13期
关键词：
copper-mediated; halogenation; alkylidenecyclopropane; stereoselective; (Z)-2,4-dihalobutene;
D O I：
10.1055/s-2003-41480
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A convenient and efficient method for the synthesis of (Z)-2,4-dihalobutenes, a useful building block in organic synthesis, was reported in good yield by the reaction of alkylidenecyclopropanes and CuX2 (or CuI/I-2).
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页码：2080 / 2082
页数：3
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